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Step Start with vinegar. Fill your spray bo.e with a solution of vinegar and water and spray the work area generously. Let the solution sit for about five minutes, then follow up with a grout brush or a scrub brush. Step Add baking soda. In a small bowl, make a paste with baking soda and water..Mold Scrubbing Tips. Leave on for as long as you need tofor example, very dirty grout can use an hour or two. Spray the tiles with water and use a scrub brush to clean the grout with a brisk back and forth motion. Rinse well and buff dry. Once it s gone, keep it gone..